AIIMS AIIMS Solved Paper-2010

  • question_answer

    Direction for: In each of the following questions a statement of Assertion is given followed by a corresponding statement of Reason just below it. Of the statements mark the correct answer as

    Assertion: \[{{S}_{N}}\text{l}\]  reaction is basically a solvolysis reaction. Reason: Polar protic solvents help the substrate to ionise and by the way get involved in \[{{S}_{N}}\text{l}\] reaction.

    A) If both Assertion: and Reason: are true and the Reason: is the correct explanation of the Assertion:

    B) If both Assertion: and Reason: are true but the Reason: is not the correct explanation of the Assertion:

    C) If Assertion: is true but Reason: is false

    D) If both Assertion: and Reason: are false

    Correct Answer: A

    Solution :

    In \[{{S}_{N}}1\] reaction, first the substrate gets ionised and then, the nucleophile attacks at the cation. To ionise a substrate, presence of polar protic solvent is necessary, thus \[{{S}_{N}}1\] reactions are basically solvolysis reactions. Hence, Reason: is the correct explanation for Assertion:.


You need to login to perform this action.
You will be redirected in 3 sec spinner