AIIMS AIIMS Solved Paper-2009

  • question_answer
    If the dissociation constant of \[=121.65nm.\] aqueous solution of diethylamine is \[3NaCNS+FeC{{l}_{3}}\xrightarrow{{}}\underset{\begin{smallmatrix}  ferric \\  sulphocyanide  \\  (blood\,red) \end{smallmatrix}}{\mathop{Fe{{(CNS)}_{3}}}}\,+3NaCl\], its pH value is

    A) \[N{{a}_{2}}{{B}_{4}}{{O}_{7}}\xrightarrow{{{740}^{o}}C}2\underbrace{2\underset{\begin{smallmatrix}  sodium \\  metaborate \end{smallmatrix}}{\mathop{NaB{{O}_{2}}}}\,+\underset{\begin{smallmatrix}  boric \\  anhydride \end{smallmatrix}}{\mathop{{{B}_{2}}{{O}_{3}}}}\,}_{glassy\,\,bead}\]                                

    B) \[W=\frac{EN\,V}{1000}\]           

    C)        \[N=\frac{1.575\times 1000}{63\times 250}\]                     

    D)        \[\because \]

    Correct Answer: C

    Solution :

    Diethylamine is a weak base and from Ostwalds dilution law, for weak base, \[\therefore \] \[a=395.6pm\]  \[=\frac{ZM}{{{N}_{a}}a}\] \[d=\frac{2\times 23}{6.023\times {{10}^{23}}\times {{(3.956)}^{3}}\times {{10}^{-24}}}\] \[=1.23g/cc.\]  \[(HN{{O}_{3}})\] \[(NO),N{{O}_{2}}\] \[{{H}_{2}}S\]   \[2HN{{O}_{3}}+NO\xrightarrow{{}}{{H}_{2}}O+3N{{O}_{2}}\]


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