AIIMS AIIMS Solved Paper-2008

  • question_answer
    3-hyroxybutanal is formed when X reacts with Y in dilute Z solution. What are X, Y and Z?

    A) X                                             Y                              Z  \[BaS{{O}_{4}}\]                              \[CaS{{O}_{4}}\]                \[(Ag+Pb)\,alloy\,\,\xrightarrow[Zinc\,is\,added]{Melt\,and}(Ag+Pb+Zn)melt\]

    B)  \[\xrightarrow{Cool}\,\,\xrightarrow[Layer\,Y]{Layer\,X}\]                         \[Zn\]    \[Ag\]

    C)  \[Pb\]                  \[Ag\]   \[{{S}^{2-}}\]

    D)  \[SO_{3}^{2-}\]                                \[{{(C{{H}_{3}}COO)}_{2}}Pb\]   \[N{{a}_{2}}[Fe{{(CN)}_{5}}NO]\]

    Correct Answer: D

    Solution :

                     Aldehyde having cc-H-atoms undergo aldol condensation in the presence of dil. \[_{3}L{{i}^{6}}\] and yield \[Br-CH=C{{(C{{H}_{3}})}_{2}}\]-hydroxy aldehydes. \[C{{H}_{2}}=CH-CH(C{{H}_{3}})-C{{H}_{2}}Br\]


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