AIIMS AIIMS Solved Paper-2005

  • question_answer
    Which of the following chemicals are used to manufacture methyl isocyanate that caused Bhopal Tragedy? (i) Methylamine               (ii) Phosgene (iii) Phosphine                   (iv) Dimethylamine

    A) (i) and (iii)    

    B)        (iii) and (iv)        

    C)        (i) and (ii)            

    D)        (ii) and (iv)

    Correct Answer: C

    Solution :

    Methyl isocyanate \[MIC\,\,\,(C{{H}_{3}}NCO)\]  is industrially prepared by the reaction of methyl amine and phosgene (carbonyl chloride) \[\underset{Methyl\,a\min e}{\mathop{C{{H}_{3}}N{{H}_{2}}}}\,+\underset{Phosgene}{\mathop{COC{{l}_{2}}}}\,\xrightarrow{-HCl}[C{{H}_{3}}NH-CO-Cl]\]                                      \[\xrightarrow[-HCl]{\Delta }\underset{Methyl\,isocyanate}{\mathop{C{{H}_{3}}N=C=O}}\,\] On the night of Dec. 2, 1984, a major gas tragedy struck Bhopal due to leakage of MIC from storage tank of Union Carbide Ltd. Plant, MIC was used in the manufacture of insecticide.


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