AIIMS AIIMS Solved Paper-2002

  • question_answer
    The mass of 70% \[{{H}_{2}}S{{O}_{4}}\] required for neutralization of one mole of \[NaOH\] is:

    A)  70 g                      

    B)         35 g                      

    C)  30 g                      

    D)         95 g                   

    Correct Answer: A

    Solution :

    The neutralization of \[NaOH\] and \[{{H}_{2}}S{{O}_{4}}\] take place as follows \[2NaOH+{{H}_{2}}S{{O}_{4}}\xrightarrow{{}}N{{a}_{2}}S{{O}_{4}}+{{H}_{2}}O\] 2 mole of \[NaOH\] is neutralized by 1 mole \[\therefore \]1 mole \[NaOH\] is neutralized by \[\frac{1}{2}\] mole \[NaOH\]. Given 70% \[{{H}_{2}}S{{O}_{4}}\] i.e., 70 g of \[{{H}_{2}}S{{O}_{4}}\] is dissolved in 100 mL acid Mol. mass of \[{{H}_{2}}S{{O}_{4}}\] \[=1\times 2+32\times 1+16\times 4=98g\] 1 mole of \[{{H}_{2}}S{{O}_{4}}=98g\]  \[\frac{1}{2}\]mol \[{{H}_{2}}S{{O}_{4}}=49g\] 70 g \[{{H}_{2}}S{{O}_{4}}\] is present in 100 g acid \[\therefore \] 49 g will be present in \[\frac{100}{70}\times 49=70\text{ }g\] acid


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