JEE Main & Advanced AIEEE Solved Paper-2006

  • question_answer
    The decreasing values of bond angles from\[N{{H}_{3}}(107{}^\circ )\]to\[Sb{{H}_{3}}(91{}^\circ )\]down group-15 of the periodic table is due to     AIEEE  Solved  Paper-2006

    A) increasing\[bp-bp\]repulsion

    B) increasing p-orbital character in\[s{{p}^{3}}\]

    C) decreasing \[lp-bp\] repulsion

    D) decreasing electronegativity

    Correct Answer: D

    Solution :

    \[N{{H}_{3}}>P{{H}_{3}}>As{{H}_{3}}>Sb{{H}_{3}}\] As the electronegativity of central atom increases, bonded electron polarise towards central atom more, so, repulsion increases and bond angle increases.


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