JEE Main & Advanced AIEEE Solved Paper-2002

  • question_answer
    One of the following species acts as both Bronsted acid and base   AIEEE  Solved  Paper-2002

    A) \[{{H}_{2}}PO_{2}^{-}\]                   

    B)           \[HPO_{3}^{2-}\]

    C)           \[HPO_{4}^{2-}\]                

    D)           All of these

    Correct Answer: C

    Solution :

    \[HPO_{4}^{2-}+{{H}_{2}}O\overset{{}}{leftrightarrows}{{H}_{2}}PO_{4}^{2-}+O{{H}^{-}}\] \[HPO_{4}^{2-}+{{H}_{2}}O\overset{{}}{leftrightarrows}PO_{4}^{3-}+{{H}_{3}}{{O}^{+}}\] \[{{H}_{2}}PO_{2}^{-}\] is a conjugate base of \[{{H}_{3}}P{{O}_{2}}\] (a monobasic I acid) and does not give \[{{H}^{+}}\] further, \[HPO_{3}^{2-}\] is a conjugate base of \[{{H}_{2}}PO_{3}^{-}\] and does not ionize further, since \[{{H}_{3}}P{{O}_{3}}\] is a dibasic acid.


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