AFMC AFMC Solved Paper-2006

  • question_answer
    Which does not give a precipitate with \[\text{AgN}{{\text{O}}_{\text{3}}}\] solution?

    A) \[[Co{{(N{{H}_{3}})}_{6}}]C{{l}_{3}}\]     

    B) \[[Co{{(N{{H}_{3}})}_{5}}Cl]C{{l}_{2}}\]

    C)  \[[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]Cl\]

    D)  \[[Co{{(N{{H}_{3}})}_{3}}C{{l}_{3}}]\]

    Correct Answer: D

    Solution :

    \[[Co(N{{H}_{3}})C{{l}_{3}}]\]does not give a precipitate with \[\text{AgN}{{\text{O}}_{\text{3}}}\]solution because in it all the chlorine atoms are attached by secondary valencies.


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