AFMC AFMC Solved Paper-2004

  • question_answer
    Which of the following is the buffer solution?

    A) \[~C{{H}_{3}}COOH\text{ }+\text{ }C{{H}_{3}}COONa\]

    B) \[C{{H}_{3}}COOH+\,\,{{C}_{H3}}COON{{H}_{4}}\]

    C) \[C{{H}_{3}}COOH\text{ }+\text{ }N{{H}_{4}}Cl\]

    D) \[NaOH+NaCl\]

    Correct Answer: A

    Solution :

    A buffer solution is the solution which resist the change in pH on addition of small amount of acid or base. The ability of buffer solution to resist change in pH on addition of acid or base is called buffer action. May (i) Strong   acid   buffer:   e.g., \[HCl,HN{{O}_{3}},{{H}_{2}}S{{O}_{4}}\]etc. (ii) Strong base buffer: e.g., NaOH, KOH etc. (iii) Weak acid buffer: It is a mixture of weak acid and its salt with strong base e.g., \[C{{H}_{3}}COOH+C{{H}_{3}}COONa.\]  (iv) Weak base buffer: Mixture of weak base and its salt with strong acid e.g., \[N{{H}_{4}}OH+N{{H}_{4}}Cl.\] Buffer solutions play an important role in many industrial processes viz electroplating, manufacturing medicines, drugs etc. pH of a buffer solution can be calculated by using Henderson-Hassel Balch equation \[pH=p{{K}_{a}}+\log \frac{[salt]}{[acid]}\] \[pOH=pK{{ & }_{b}}+\log \frac{[salt]}{[base]}\]


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