JEE Main & Advanced Chemistry Structure of Atom / परमाणु संरचना Sample Paper Topic Test - Structure of Atom

  • question_answer
    For a hypothetical hydrogen like atom, the potential energy of the system is given by \[U(r)=\frac{-k{{e}^{2}}}{{{r}^{4}}}\] where r is the distance between the two particles. If Bohr's model of quantization of angular momentum is applicable, then velocity of particle is given by

    A) \[\frac{nh}{16\,ke{{\pi }^{2}}\,{{m}^{3/2}}}\]

    B) \[\frac{{{n}^{2}}{{h}^{2}}}{18\,{{k}^{2}}{{e}^{2}}{{\pi }^{2}}\,{{m}^{3}}}\]

    C) \[\frac{{{n}^{3}}{{h}^{3}}}{18\,{{k}^{2}}{{e}^{2}}{{\pi }^{3}}\,{{m}^{4}}}\]

    D) \[\frac{{{n}^{2}}{{h}^{2}}}{4\sqrt{2}\,ke{{\pi }^{2}}{{m}^{3/2}}}\]

    Correct Answer: D

    Solution :

    [d] \[\frac{d[U(r)]}{dr}=\frac{4k{{e}^{2}}}{{{r}^{5}}}=force\]
    \[\frac{4k{{e}^{2}}}{{{r}^{5}}}=\frac{m{{v}^{2}}}{r}\]
    and       \[mvr=\frac{nh}{2\pi }\]
    or         \[r=\frac{nh}{2\pi mv}\Rightarrow \frac{1}{r}=\frac{2\pi mv}{nh}\]
    \[4k{{e}^{2}}\times \frac{1}{{{r}^{5}}}=\frac{m{{v}^{2}}}{r}\]
    \[2k{{e}^{2}}\times \frac{1}{{{r}^{4}}}=m{{v}^{2}}\]
    \[2k{{e}^{2}}\times \frac{16{{\pi }^{4}}{{m}^{4}}{{v}^{4}}}{{{n}^{4}}{{h}^{4}}}=m{{v}^{2}}\]
    \[{{v}^{2}}={{n}^{4}}{{h}^{4}}/32k{{e}^{2}}{{\pi }^{4}}{{m}^{3}}\]
    \[v=\frac{{{n}^{2}}{{h}^{2}}}{4\sqrt{2}ke{{\pi }^{2}}{{m}^{3/2}}}\]


You need to login to perform this action.
You will be redirected in 3 sec spinner