NEET Sample Paper NEET Sample Test Paper-87

  • question_answer
    Which of the following reactions will not result in the formation of anisole?

    A) Phenol \[+\] dimethyl sulphate in presence of a base.

    B) Sodium phenoxide is treated with methyl iodide.

    C) Reaction of diazomethane with phenol.

    D) Reaction of methylmagnesium iodide with phenol.

    Correct Answer: D

    Solution :

    [d] Phenol has active (acidic) hydrogen so it reacts with \[C{{H}_{3}}MgI\] to give \[C{{H}_{4}},\] and not anisole \[{{C}_{6}}{{H}_{5}}OH+C{{H}_{3}}MgI\xrightarrow{{}}\] \[C{{H}_{4}}+{{C}_{6}}{{H}_{5}}OMgI\]


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