A) 1 -hydroxybutane
B) 2-hydroxybutane
C) 2-hydroxy-2-methylpropane
D) 1-hydroxy-2-methylpropane
Correct Answer: C
Solution :
\[{{(C{{H}_{3}})}_{3}}C-OH+HCl\xrightarrow{Anhyd.\,ZnC{{l}_{2}}+\,HCl}\] \[{{(C{{H}_{3}})}_{3}}C-Cl+{{H}_{2}}O\,\,3{}^\circ \] reacts immediately \[{{(C{{H}_{3}})}_{2}}CH\,\,\,-\,\,\,OH\,\,\,\,+\,\,\,HCl\,\,\xrightarrow{Anhyd\,\,ZnC{{l}_{2}}\,\,+\,\,HCl}\] \[{{(C{{H}_{3}})}_{2}}CH-Cl\,\,+\,\,{{H}_{2}}O\,\,2{}^\circ \] reacts after 5 min \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}-OH+HCl\,\,\xrightarrow{Anhyd-ZnC{{l}_{2}}+HCl}\] \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}\,\,-\,\,\,Cl\,\,+\,\,{{H}_{2}}O\,\,1{}^\circ \] reacts only on heating.
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