NEET Sample Paper NEET Sample Test Paper-6

  • question_answer
    \[{{A}_{(g)}}+3{{B}_{(g)}}4{{C}_{(g)}}\] Initially concentration of A is equal to that of B. The equilibrium concentrations of A and C are equal \[{{K}_{C}}\] is

    A)  \[0.08\]                       

    B)  \[0.8\]

    C)  \[8\]                            

    D)  \[80\]

    Correct Answer: C

    Solution :

    \[\begin{align}   & \underset{(1-x)}{\mathop{\underset{{}}{\mathop{\underset{1}{\mathop{{{A}_{(g)}}}}\,}}\,}}\,\,\,\,+\,\,\,\underset{(1-3X)}{\mathop{\underset{{}}{\mathop{\underset{1}{\mathop{3{{B}_{(g)}}}}\,}}\,}}\,\,\,\,\,\,\,\underset{4x}{\mathop{\underset{{}}{\mathop{\underset{0}{\mathop{4{{C}_{(g)}}}}\,}}\,}}\,\text{intial}\,\text{conce}\text{.} \\  & \text{final}\,\text{conc}\text{.} \\ \end{align}\] At equilibrium the concetrations of A and C are equal \[\therefore \]  \[1-x=4x\]                 \[x=\frac{1}{5}\] For above reaction             \[{{K}_{C}}=\frac{{{[C]}^{4}}}{[A]\,{{[B]}^{3}}}=\frac{{{(4x)}^{4}}}{(1-x)\,{{(1-3x)}^{3}}}\]                 \[{{K}_{C}}=\frac{{{\left( 4\times \frac{1}{5} \right)}^{4}}}{\left( 1-\frac{1}{5} \right){{\left( 1-3\times \frac{1}{5} \right)}^{3}}}=8.0\]


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