NEET Sample Paper NEET Sample Test Paper-60

  • question_answer
    Which of the following halides is most acidic?

    A) \[PC{{l}_{3}}\]            

    B) \[SbC{{l}_{3}}\]

    C) \[BiC{{l}_{3}}\]                       

    D) \[CC{{l}_{4}}\]

    Correct Answer: A

    Solution :

    [a] \[PC{{l}_{3}}\] In \[CC{{l}_{4}},\] carbon atom does not have empty d-orbitals to accommodate a lone pair of electrons and hence is not a lewis acid. In \[PC{{l}_{3}}\],\[SbC{{l}_{3}}\]and \[BiC{{l}_{3}}\]central atom has empty d-orbitals in each case but electronegativity of P is maximum hence \[PC{{l}_{3}}\] is strongest lewis acid.


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