NEET Sample Paper NEET Sample Test Paper-53

  • question_answer
    On treatment of 100 ml of 0.1 M solution of the complex \[CoC{{l}_{3}}.6{{H}_{2}}O\] with excess of \[AgN{{O}_{3}},\,\,4.305g\] of \[AgCl\] was obtained. The complex is-

    A) \[\left[ Co{{\left( {{H}_{2}}O \right)}_{6}} \right]C{{l}_{3}}\]

    B) \[\left[ Co\left( {{H}_{2}}O \right)5Cl \right]C{{l}_{2}}.{{H}_{2}}O\]

    C) \[\left[ Co{{\left( {{H}_{2}}O \right)}_{3}}C{{l}_{3}} \right].3{{H}_{2}}O\]

    D) \[\left[ Co{{\left( {{H}_{2}}O \right)}_{4}}C{{l}_{2}} \right]Cl.2{{H}_{2}}O\]

    Correct Answer: A

    Solution :

    As mol of \[AgCl\,\,=\,\,\frac{4.305}{143.5}\,\,=\,\,0.03\] = mol of \[C{{l}^{-}}\] given by complex mol of the complex \[=\text{ }100\,\,\times \,\,{{10}^{-}}^{3}\times 1\,\,=\,\,0.01\] \[\left[ Co{{\left( {{H}_{2}}O \right)}_{6}} \right]C{{l}_{3}}\to \,\,\,{{\left[ Co{{\left( {{H}_{2}}O \right)}_{6}} \right]}^{+}}^{3}+\,\,3C{{l}^{-}}\]         0.01 mole                       0.03 mole


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