NEET Sample Paper NEET Sample Test Paper-45

  • question_answer
    In a first order reaction the concentration of reactant decreases from 800 mol/\[d{{m}^{3}}\] to \[50\text{ }mol/d{{m}^{3}}\] is \[2\,\,\times \,\,{{10}^{2}}\] sec. The rate constant of reaction in \[sec{{\,}^{-}}^{1}\] is:

    A) \[2\,\,\times \,\,{{10}^{4}}~\]              

    B) \[3.45\times {{10}^{-}}^{5}\]

    C) \[1.386\times {{10}^{-}}^{2}\]                       

    D) \[2\,\,\times \,\,{{10}^{-}}^{4}\]

    Correct Answer: C

    Solution :

    \[k=\frac{2.303}{t}\,{{\log }_{10}}\,\frac{a}{a-x}\] \[t=2\times {{10}^{2}},\,\,\,a=800,\,\,\,a-x=50\] \[k=\frac{2.303}{2\times {{10}^{2}}}{{\log }_{10}}\,\frac{800}{50}\,\,=\,\,\frac{2.303}{2\times {{10}^{2}}}\,{{\log }_{10}}\,16\] \[=\frac{2.303}{2\times {{10}^{2}}}{{\log }_{10}}\,{{2}^{4}}=\,\,\frac{2.303}{2\times {{10}^{4}}}\times \,4\times 0.301\] \[=1.38\times {{10}^{-2}}\,{{s}^{-1}}\]


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