KVPY Sample Paper KVPY Stream-SX Model Paper-10

  • question_answer
    Consider the following compound:
    [a]\[{{\operatorname{IF}}_{5}}\] [b]  \[{{\operatorname{CII}}^{-}}_{4}\]
    [c] \[{{\operatorname{XeO}}_{2}}{{F}_{2}}\] [d] \[{{\operatorname{NH}}^{-}}_{2}\]
    [e] \[{{\operatorname{BCl}}_{3}}\] [f] \[{{\operatorname{BeCl}}_{2}}\]
    [g] \[\operatorname{B}{{\left( OH \right)}_{3}}\]
    If x, y and z are total number of compounds in Which central atom used their all three p-orbitals, Only two p-orbitals and only one p-orbital in Hybridisation respectively. Then value of"\[''x + y - z'' is\]

    A) 5                                 

    B) 3

    C) 4                                 

    D) 2

    Correct Answer: A

    Solution :

    (i) \[{{\operatorname{IF}}_{5}}\left( s{{p}^{3}}d \right)\] (ii) \[\operatorname{CII}_{4}^{-}\left( s{{p}^{3}}{{d}^{2}} \right)\]
    (iii) \[{{\operatorname{XeO}}_{2}}{{F}_{2}}\left( s{{p}^{3}}d \right)\] (iv) \[\operatorname{NH}_{2}^{-}\left( s{{p}^{3}} \right)\]
    (v) \[{{\operatorname{BCl}}_{3}}\left( s{{p}^{2}} \right)\] (vi) \[BeC{{l}_{2}}\left( sp \right)\]
    (vii) \[B{{\left( OH \right)}_{3}}\left( s{{p}^{2}} \right)\]
    \[x=4,y=2,z=1\]
    \[\therefore x+y-z=4+2-1=5\]


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