JEE Main & Advanced Sample Paper JEE Main Sample Paper-46

  • question_answer
    Some half-cell reactions and their standard potentials are given as below:
    \[MnO_{4}^{-}(aq)+8{{H}^{+}}(aq)+5{{e}^{-}}\xrightarrow{\,}\,M{{n}^{2+}}(aq)+4{{H}_{2}}O(l);\]\[{{E}^{o}}=1.51\,\,V\]
    \[C{{r}_{2}}O_{7}^{2-}(aq)+14{{H}^{+}}(aq)+6{{e}^{-}}\to 2C{{r}^{3+}}(aq)+7{{H}_{2}}O(l);\] \[{{E}^{o}}=1.38\,\,V\]
    \[F{{e}^{3+}}(aq)+{{e}^{-}}\xrightarrow{\,}\,F{{e}^{2+}}(aq);\]\[{{E}^{o}}=0.77\,\,V\]
    \[C{{l}_{2}}(g)+2{{e}^{-}}\xrightarrow{\,}\,2C{{l}^{-}}(aq);\]\[{{E}^{o}}=1.40\,\,V\]
    Identify the incorrect statement.

    A)  \[MnO_{4}^{-}\]is weaker oxidizing agent than \[C{{l}_{2}}\]  

    B)  \[C{{r}_{2}}O_{7}^{2-}\] is weaker oxidizing agent than \[C{{l}_{2}}\]

    C)  \[MnO_{4}^{-}\]is stronger oxidizing agent than \[F{{e}^{3+}}\]

    D)  \[C{{r}_{2}}O_{7}^{2-}\]is weaker oxidizing agent than \[MnO_{4}^{-}\]

    Correct Answer: A

    Solution :

     Standard reeducation potential of \[MnO_{4}^{-}\] is greater than that of other three. So, it is a stronger oxidizing agent than the other. Other statements are correct.


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