JEE Main & Advanced Sample Paper JEE Main Sample Paper-3

  • question_answer
    To detect iodine in presence of bromine, the sodium extract is treated with \[NaN{{O}_{2}}+\]glacial acetic acid \[+\text{ }CC{{l}_{4}}.\]Iodine is detected by the appearance of

    A)  yellow colour of \[CC{{l}_{4}}\]layer

    B)  purple colour of\[CC{{l}_{4}}\]

    C)  brown colour in the organic layer of\[CC{{l}_{4}}\]

    D)  deep blue colour in\[CC{{l}_{4}}\]

    Correct Answer: B

    Solution :

     \[2NaI+2NaN{{O}_{2}}+4C{{H}_{3}}COOH\xrightarrow[{}]{{}}{{I}_{2}}+2NO+\]\[4C{{H}_{3}}COONa+2{{H}_{2}}O\] The colour of \[CC{{l}_{4}}\] layer turns purple due to liberated\[{{I}_{2}}\].


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