JEE Main & Advanced Sample Paper JEE Main Sample Paper-32

  • question_answer
    In the formation of \[HBr\] from \[{{H}_{2}}\] & \[B{{r}_{2}}\], following mechanism is observed.
    [1] \[B{{r}_{2}}2Br\centerdot \]Equilibrium step
    [2] \[{{H}_{2}}+Br\centerdot \xrightarrow{{}}HBr+H\centerdot \]Slow step
    [3]\[H\centerdot +B{{r}_{2}}\xrightarrow{{}}HBr+Br\centerdot \] Fast step
    Calculate the rate of reaction, if concentration of hydrogen is twice that of bromine and the rate constant is equal to \[I{{M}^{-1/2}}Se{{c}^{-1}}\]. Concentration of bromine is 1M.

    A) \[2M\,Se{{c}^{-1}}\] 

    B)     \[3M\,Se{{c}^{-1}}\]

    C) \[4M\,Se{{c}^{-1}}\]        

    D)    \[5M\,Se{{c}^{-1}}\]

    Correct Answer: A

    Solution :

    Rate \[=K{{[{{H}_{2}}]}^{1}}\,{{[B{{r}_{2}}]}^{1/2}}\] Rate \[=1\,{{[2]}^{1}}{{[1]}^{1/2}}=2\,Se{{c}^{-1}}\]


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