JEE Main & Advanced Sample Paper JEE Main Sample Paper-25

  • question_answer
    An acid halide (X) reacts with excess of Grignard reagent (Y), the product can be :

    A)  \[Ph-\underset{\begin{smallmatrix}  | \\  OH \end{smallmatrix}}{\mathop{\overset{\begin{smallmatrix}  Ph \\  | \end{smallmatrix}}{\mathop{C}}\,}}\,-Ph\]       

    B)  \[Ph-\underset{\begin{smallmatrix}  | \\  OH \end{smallmatrix}}{\mathop{\overset{\begin{smallmatrix}  Me \\  | \end{smallmatrix}}{\mathop{C}}\,}}\,-Et\]

    C)  \[H-\underset{\begin{smallmatrix}  | \\  OH \end{smallmatrix}}{\mathop{\overset{\begin{smallmatrix}  Me \\  | \end{smallmatrix}}{\mathop{C}}\,}}\,-Et\]        

    D)  \[Me-\underset{\begin{smallmatrix}  || \\  OH \end{smallmatrix}}{\mathop{C}}\,-Et\]

    Correct Answer: A

    Solution :

    \[\underset{(excess)}{\mathop{R-\overset{\begin{smallmatrix}  O \\  \,|| \end{smallmatrix}}{\mathop{C}}\,-OR'\,+R''MgX\xrightarrow{\,}R-\overset{\begin{smallmatrix}  O \\  \,|| \end{smallmatrix}}{\mathop{C}}\,-R'\,+R-\underset{\begin{smallmatrix}  \,\,\,| \\  \,\,R' \end{smallmatrix}}{\overset{\begin{smallmatrix}  \,\,OH \\  \,\,\,\,\,\,|\,\, \end{smallmatrix}}{\mathop{C}}}\,-R''}}\,\]


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