JEE Main & Advanced Sample Paper JEE Main Sample Paper-10

  • question_answer
    What will be the empirical formula of organic compound. If in Carius method 0.099 g organic compound gave 0.287 g\[Agcl\]and it contain 24% carbon and 4.3% of hydrogen?

    A)  \[C{{H}_{2}}C{{l}_{2}}\]                               

    B)  \[C{{H}_{2}}Cl\]

    C)  \[CHC{{l}_{3}}\]              

    D)  \[{{C}_{2}}{{H}_{4}}C{{l}_{2}}\]

    Correct Answer: B

    Solution :

     This problem includes conceptual mixing of determination of amount of percentage of element in organic compound and empirical formula. Quantitative determination of amount of percentage of Cl % of chlorine \[=\frac{35.5}{143.5}\times \frac{\text{mass of }AgCl}{\text{mass of the compound}}\times 100\] \[=\frac{35.5}{143.5}\times \frac{0.287}{0.099}\times 100=71.71%\] Determination of empirical formula
    Symbol Percentage Atomic Relativ number of atoms
    C H Cl 24 4.3 71.1  12 1 35.5 \[\frac{24}{12}=2\] \[\frac{4.3}{1}=4.3\approx 4\] \[\frac{71.7}{35.5}\approx 2\]
    Empirical formula \[=(C{{H}_{2}}Cl)\]


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