JEE Main & Advanced Chemistry Solutions / विलयन Question Bank Topic Test - Solutions

  • question_answer
    Calculate the weight of non-volatile solute having molecular weight 40, which should be dissolved in 57 g octane to reduce its vapor pressure to 80%:

    A) 47.2 g

    B) 5g          

    C) 106.2g

    D) None of these

    Correct Answer: B

    Solution :

    [b] \[{{P}_{s}}=\left( \frac{80}{100} \right){{P}^{o}},w=?\]
    \[{{M}_{solute}}=40,\,w=114g,\,{{M}_{solvent}}=114\]
                \[\frac{P_{{}}^{O}-{{P}_{s}}}{{{P}_{s}}}=\frac{w\times {{M}_{solvent}}}{{{M}_{solute}}\times W}\]
    or         \[\frac{P_{{}}^{O}-\left( 80/100 \right){{P}^{O}}}{\left( 80/100 \right){{P}^{O}}}=\frac{w\times 114}{40\times 57}\]
    \[\therefore \]    \[w=5g\]


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