JEE Main & Advanced Chemistry Solutions / विलयन Question Bank Topic Test - Solutions

  • question_answer
    Maximum freezing point will be for 1 molal solution of assuming equal ionization in each case

    A) \[[Fe{{({{H}_{2}}O)}_{6}}]C{{l}_{3}}\]

    B) \[[Fe{{({{H}_{2}}O)}_{5}}Cl]C{{l}_{2}}.{{H}_{2}}O\]

    C) \[[Fe{{({{H}_{2}}O)}_{4}}C{{l}_{2}}]Cl.\,2{{H}_{2}}O\]

    D) \[[Fe{{({{H}_{2}}O)}_{3}}C{{l}_{3}}].\,3{{H}_{2}}O\]

    Correct Answer: D

    Solution :

    [d] In 4 option their is no ionization
    \[\Delta {{T}_{f}}\propto {{i}^{o}}\]
    \[F.P=0-\Delta {{T}_{f}}\]
    Hence greater the value of \[\Delta {{T}_{f}},\] smaller the F.P. hence maximum freezing points is of '4' option.


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