JEE Main & Advanced Chemistry The p-block Elements-II / p-ब्लॉक तत्व-II Question Bank Self Evaluation Test - The p-Block Elements (Group 15, 16, 17 & 18)

  • question_answer
    From the following information \[X+{{H}_{2}}S{{O}_{4}}\to Y\] (a colourless arid irritating gas) \[Y+{{K}_{2}}C{{r}_{2}}+{{H}_{2}}S{{O}_{4}}\to \] (green coloured solution) Identify the pair X and Y.

    A) \[\overline{C}r,HCl\]                  

    B) \[SO_{3}^{2-},S{{\text{O}}_{2}}\]

    C) \[{{S}^{2-}},{{H}_{2}}S\]                 

    D) \[CO_{3}^{2-},C{{O}_{2}}\]

    Correct Answer: B

    Solution :

    [b] \[\underset{(X)}{\mathop{SO_{3}^{2-}}}\,+2{{H}^{\oplus }}\to S{{O}_{2}}+{{H}_{2}}O\] \[\underset{(Y)}{\mathop{3S{{O}_{2}}}}\,+{{K}_{2}}C{{r}_{2}}{{O}_{7}}+{{H}_{2}}S{{O}_{4}}\to \] \[{{K}_{2}}S{{O}_{4}}+\underset{\begin{smallmatrix}  Green\text{ }coloured\text{ } \\  solution \end{smallmatrix}}{\mathop{C{{r}_{2}}{{(S{{O}_{4}})}_{2}}+{{H}_{2}}O}}\,\]


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