NEET Chemistry Solutions / विलयन Question Bank Self Evaluation Test - Solutions

  • question_answer
    \[{{\pi }_{1}},{{\pi }_{2}},{{\pi }_{3}}\] and \[{{\pi }_{4}}\] atm are the osmotic pressures of 5% (mass/volume) solutions of urea, fructose, sucrose and \[KCl\] respectively at certain temperature. The correct order of their magnitudes is:

    A) \[{{\pi }_{1}}>{{\pi }_{4}}>{{\pi }_{2}}>{{\pi }_{3}}\]  

    B) \[{{\pi }_{1}}>{{\pi }_{4}}>{{\pi }_{2}}>{{\pi }_{3}}\]

    C) \[{{\pi }_{4}}>{{\pi }_{1}}>{{\pi }_{2}}>{{\pi }_{3}}\]         

    D) \[{{\pi }_{4}}>{{\pi }_{1}}>{{\pi }_{3}}>{{\pi }_{2}}\]

    Correct Answer: C

    Solution :

    [c] Moles of urea \[=\frac{5}{60};\] moles of fructose \[=\frac{5}{180};\] \[{{C}_{urea}}=\frac{0.08\times 1000}{100}\Rightarrow 0.833\] moles of sucrose \[=\frac{5}{342};\] \[{{C}_{sucrose}}=0.0146\times \frac{1000}{100}=0.146\] moles of \[KCl\] (effective) \[=2\times \frac{5}{74.5}=\frac{5}{37.25};\frac{0.134\times 1000}{100}=1.34\] \[\pi \propto C\] this order is \[{{\pi }_{4}}>{{\pi }_{1}}>{{\pi }_{2}}>{{\pi }_{3}}\]


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