NEET Chemistry Organic Chemistry: Some Basic Principles & Techniques / कार्बनिक रसायन : कुछ मूलभूत सिद्धांत एवं तकन Question Bank Self Evaluation Test - Organic Chemistry - Some Basic Principles & Techniques

  • question_answer
    The optically inactive compound from the following is:

    A) 2 - chloropropanal

    B) 2 - chlorobutane

    C) 2 - chloropentane

    D) 2 - chloro - 2- methylbutane

    Correct Answer: D

    Solution :

    [d] The optically inactive compound must contains achiral carbon atom(s). Option [d] contains achiral carbon atom \[\underset{2-chloropropanol}{\mathop{C{{H}_{3}}-\underset{H}{\overset{Cl}{\mathop{\underset{|}{\overset{|}{\mathop{C}}}\,}}}\,-CHO}}\,\]                    \[\underset{2-\text{chlorobutane}\,\,\,\,\,\text{(chiral)}}{\mathop{C{{H}_{3}}-C{{H}_{2}}-\underset{H}{\mathop{\overset{Cl}{\mathop{\underset{|}{\mathop{\overset{|}{\mathop{C}}\,}}\,}}\,}}\,-C{{H}_{3}}}}\,\]  \[\underset{2-\text{chloropentane}\,\,\text{(chiral)}}{\mathop{C{{H}_{3}}-C{{H}_{2}}-C{{H}_{2}}-\underset{H}{\mathop{\overset{Cl}{\mathop{\underset{|}{\mathop{\overset{|}{\mathop{C}}\,}}\,}}\,}}\,-C{{H}_{3}}}}\,\] \[\underset{2-\text{chloro}-2-\text{methylbutane}\,\,\,\text{(achira)}}{\mathop{C{{H}_{3}}-C{{H}_{2}}-\underset{Cl}{\mathop{\overset{C{{H}_{3}}}{\mathop{\underset{|}{\mathop{\overset{|}{\mathop{C}}\,}}\,}}\,}}\,-C{{H}_{3}}}}\,\]


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