JEE Main & Advanced Chemistry Classification of Elements and Periodicity in Properties / तत्त्वों का वर्गीकरण एवं गुणों में आवर्ति Question Bank Self Evaluation Test - Classification of Elements and Periodicity in Properties

  • question_answer
    Consider the following ionization enthalpies of two elements 'A' and 'B'.
    Elements 1st Lionization 2nd Enthalpy (KJ/mol)
    A 899 1757 14847
    B 737 1450 7731
    Which of the following statements is correct?

    A) Both 'A' and 'B' belong to group-1 where 'B' comes below 'A'.

    B) Both 'A' and 'B' belong to group-1 where 'A' comes below 'B.

    C) Both 'A' and 'B' belong to group-2 where 'B' comes below 'A'.

    D) Both 'A' and 'B' belong to group-2 where 'A' comes below 'B'.

    Correct Answer: C

    Solution :

    [c] Generally, the ionization enthalpies or energy increases from left to right in a period and decreases from top to bottom in a group. Several factor such as atomic radius, nuclear charge, shielding effect are responsible for change of ionization enthalpies. Here, 1st ionization enthalpy of A and B is greater than group-1 (\[Li=520\text{ }kJmo{{l}^{-1}}\] to \[Cs=374\text{ }kJmo{{l}^{-1}}\]), which means element A and B belong to group-2 and all three given ionization enthalpy values are less for element B means B will come below A.


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