JEE Main & Advanced Chemistry Chemical Bonding and Molecular Structure / रासायनिक आबंधन एवं आणविक संरचना Question Bank Self Evaluation Test - Chemical Bonding and Molecular Structure

  • question_answer
    The internuclear distances in \[~O-O\] bonds for \[O_{2}^{+},{{O}_{2}},O_{2}^{-}\] and \[O_{2}^{2-}\] respectively are:

    A) \[1.30\overset{\text{o}}{\mathop{\text{A}}}\,,\text{ }1.49\overset{\text{o}}{\mathop{\text{A}}}\,,\text{ }1.12\overset{\text{o}}{\mathop{\text{A}}}\,,\text{ }1.21\overset{\text{o}}{\mathop{\text{A}}}\,\]

    B) \[1.49\overset{\text{o}}{\mathop{\text{A}}}\,,\text{ }1.21\overset{\text{o}}{\mathop{\text{A}}}\,,\text{ }1.12\overset{\text{o}}{\mathop{\text{A}}}\,,\,1.30\overset{\text{o}}{\mathop{\text{A}}}\,\]

    C) \[1.21\overset{\text{o}}{\mathop{\text{A}}}\,,\text{ }1.12\overset{\text{o}}{\mathop{\text{A}}}\,,\text{ }1.49\overset{\text{o}}{\mathop{\text{A}}}\,,\text{ }1.30\overset{\text{o}}{\mathop{\text{A}}}\,\]

    D) \[1.12\overset{\text{o}}{\mathop{\text{A}}}\,,\text{ }1.21\overset{\text{o}}{\mathop{\text{A}}}\,,\text{ }1.30\overset{\text{o}}{\mathop{\text{A}}}\,,\text{ }1.49\overset{\text{o}}{\mathop{\text{A}}}\,\]

    Correct Answer: D

    Solution :

    [d] The bond length follows the order \[O_{2}^{+}<{{O}_{2}}<O_{_{2}}^{-}<O_{2}^{2-}~\] According to this the possible values are \[1.12\overset{\text{o}}{\mathop{\text{A}}}\,,\text{ }1.21\overset{\text{o}}{\mathop{\text{A}}}\,,\text{ }1.30\overset{\text{o}}{\mathop{\text{A}}}\,,\text{ }1.49\overset{\text{o}}{\mathop{\text{A}}}\,\]


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