JEE Main & Advanced Chemistry Chemical Bonding and Molecular Structure / रासायनिक आबंधन एवं आणविक संरचना Question Bank Self Evaluation Test - Chemical Bonding and Molecular Structure

  • question_answer
    Molecular AB has a bond length of \[1.61\overset{\text{o}}{\mathop{\text{A}}}\,\]and a dipole moment of 0.38 D. The fractional charge on each atom (absolute magnitude) is: \[(e=4.802\times {{10}^{-10}}esu)\]

    A) 0.5                   

    B) 0.05  

    C) 0                                 

    D) 1.0

    Correct Answer: B

    Solution :

    [b] \[1e=1.602\times {{10}^{-19}}C\] \[1\,esu=3.33\times {{10}^{-10}}C\] \[\frac{1e}{1\,esu}=\frac{1.602\times {{10}^{-19}}C}{3.33\times {{10}^{-10}}C}\] \[1e=4.802\times {{10}^{-10}}esu\] \[Dipole\text{ }moment=q\times distance\]  \[\Rightarrow 1\,D\approx {{10}^{-18}}esucm\]  \[0.38\times {{10}^{-18}}esu\,cm=q\times (1.61\times {{10}^{-18}}cm)\] \[q=2.36\times {{10}^{-11}}esu\] \[q=\frac{2.36\times {{10}^{-11}}esu}{4.802\times {{10}^{-10}}esu}\] \[q=0.049\] \[q\approx 0.05\]fractional charge


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