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JEE Main & Advanced Chemistry Nitrogen Containing Compounds Question Bank Self Evaluation Test - Amines

  • question_answer
    A compound 'A' when treated with \[HN{{O}_{3}}\] (in presence of \[{{H}_{2}}S{{O}_{4}}\]) gives compound 'B' which is then reduced with Sn and \[HCl\] to aniline? The compound 'A' is

    A) toluene             

    B) benzene

    C) ethane              

    D) acetamide

    Correct Answer: B

    Solution :

    [b] \[A\xrightarrow{HN{{O}_{3}}/{{H}_{2}}S{{O}_{4}}}B\xrightarrow{Sn/HCl}{{C}_{6}}{{H}_{5}}N{{H}_{2}}\] This indicates that B is \[{{C}_{6}}{{H}_{5}}N{{O}_{2}}\] and hence A is \[{{C}_{6}}{{H}_{6}}\]


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