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JEE Main & Advanced Chemistry Nitrogen Containing Compounds Question Bank Self Evaluation Test - Amines

  • question_answer
    Hydrolysis of \[C{{H}_{2}}C{{H}_{2}}N{{O}_{2}}\] with 85% \[{{H}_{2}}S{{O}_{\text{4}}}\]gives

    A) \[C{{H}_{3}}C{{H}_{2}}OH\]             

    B) \[{{C}_{2}}{{H}_{6}}\]

    C) \[C{{H}_{3}}CH=NOH\]          

    D) \[C{{H}_{3}}COOH\]

    Correct Answer: D

    Solution :

    [d] \[1{}^\circ \] Nitroalkanes on hydrolysis with boiling 85% \[{{H}_{2}}S{{O}_{4}}\] give acids. \[C{{H}_{3}}C{{H}_{2}}N{{O}_{2}}+{{H}_{2}}O+{{H}_{2}}S{{O}_{4}}\xrightarrow{heat}\] \[C{{H}_{3}}COOH+{{\left[ N{{H}_{3}}OH \right]}^{+}}HSO_{4}^{-}\]


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