JEE Main & Advanced Chemistry Nitrogen Containing Compounds Question Bank Self Evaluation Test - Amines

  • question_answer
    \[C{{H}_{3}}-C{{H}_{2}}C\equiv N\xrightarrow{X}C{{H}_{3}}C{{H}_{2}}CHO\]. The compound X is

    A) \[SnC{{l}_{2}}/HCl/{{H}_{2}}O,boil\]

    B) \[{{H}_{2}}/Pd-BaS{{O}_{4}}\]

    C) \[LiAI{{H}_{4}}/ether\]

    D) \[NaB{{H}_{4}}/ether/{{H}_{3}}{{O}^{+}}\]

    Correct Answer: A

    Solution :

    [a] It is Stephen's reaction. \[C{{H}_{3}}C{{H}_{2}}C\equiv N\xrightarrow{SnC{{l}_{2}}/HCl}C{{H}_{3}}C{{H}_{2}}CH\equiv NH.HCl\] \[\xrightarrow{{{H}_{2}}O}C{{H}_{3}}C{{H}_{2}}CHO+N{{H}_{4}}Cl\]


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