NEET Chemistry Aldehydes, Ketones Question Bank Self Evaluation Test - Aldehydes, Ketons and Carboxylic Acids

  • question_answer
    Which of the following compounds will react with \[NaHC{{O}_{3}}\] solution to give sodium salt and carbon dioxide?

    A) Acetic acid      

    B) n-Hexanol

    C) Phenol                          

    D) Both [b] and [c]

    Correct Answer: A

    Solution :

    [a] Only acetic acid is more acidic than carbonic acid (conjugate acid of\[NaHC{{O}_{3}}\]) hence it dissolves in \[NaHC{{O}_{3}}\] \[\underset{stronger\text{ }acid}{\mathop{C{{H}_{3}}COOH}}\,+NaHC{{O}_{3}}\xrightarrow{{}}\] \[C{{H}_{3}}CO{{O}^{-}}N{{a}^{+}}+\underset{weaker\text{ }acid}{\mathop{{{H}_{2}}C{{O}_{3}}}}\,\left( {{H}_{2}}O+C{{O}_{2}} \right)\] while phenol and n-hexanol are less acidic than carbonic acid and hence do not dissolve in \[NaHC{{O}_{3}}\].


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