NEET Chemistry Aldehydes, Ketones Question Bank Self Evaluation Test - Aldehydes, Ketons and Carboxylic Acids

  • question_answer
    In the following sequence of reactions, what is D?    \[A\xrightarrow{SOC{{l}_{2}}}B\xrightarrow{Na{{N}_{3}}}C\xrightarrow{heat}D\]

    A) Primary amine

    B) An amide

    C) Phenyl isocyanate

    D) A higher hydrocarbon

    Correct Answer: C

    Solution :

    [c] \[{{C}_{6}}{{H}_{5}}C{{H}_{3}}\xrightarrow{[O]}\underset{[A]}{\mathop{{{C}_{6}}{{H}_{5}}COOH}}\,\xrightarrow{SOC{{l}_{2}}}\] \[\underset{[B]}{\mathop{{{C}_{6}}{{H}_{5}}COCl}}\,\xrightarrow{Na{{N}_{3}}}\underset{[C]}{\mathop{{{C}_{6}}{{H}_{5}}CO{{N}_{3}}}}\,\] \[\xrightarrow{heat}\underset{Unstable\,Bemzoyl\,nitrene}{\mathop{\left[ {{C}_{6}}{{H}_{5}}-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-\overset{..}{\mathop{N}}\,: \right]}}\,\xrightarrow{{}}\underset{Phenyl\,isocyanate,[D]}{\mathop{{{C}_{6}}{{H}_{5}}NCO}}\,\]


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