NEET Chemistry Alcohols, Phenols and Ethers / एल्कोहॉल, फीनॉल तथा ईथर Question Bank Self Evaluation Test - Alcohols, Phenols and Ethers

  • question_answer
    Which of the following are intermediates in the reaction of excess of \[C{{H}_{3}}MgBr\] with \[{{C}_{6}}{{H}_{5}}COO{{C}_{2}}{{H}_{5}}\] to make 2-phenyl - 2-propanol?
    A. \[{{C}_{6}}{{H}_{5}}-\underset{C{{H}_{3}}}{\overset{OMgBr}{\mathop{\underset{|}{\overset{|}{\mathop{C}}}\,}}}\,-OC{{H}_{2}}C{{H}_{3}}\]
    B. \[{{C}_{6}}{{H}_{5}}-\underset{{}}{\overset{O}{\mathop{\underset{{}}{\overset{||}{\mathop{C}}}\,}}}\,-C{{H}_{3}}\]
    C. \[{{C}_{6}}{{H}_{5}}-\underset{C{{H}_{3}}}{\overset{OMgBr}{\mathop{\underset{|}{\overset{||}{\mathop{C}}}\,}}}\,-C{{H}_{3}}\]

    A) A and B 

    B) A, B and C

    C) A and C           

    D) B and C

    Correct Answer: B

    Solution :

    [b] \[{{C}_{6}}{{H}_{5}}-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-O{{C}_{2}}{{H}_{5}}+C{{H}_{3}}MgBr\xrightarrow{{}}\] \[\underset{(A)}{\mathop{{{C}_{6}}{{H}_{5}}-\underset{C{{H}_{3}}}{\mathop{\underset{|}{\mathop{\overset{OMgBr}{\mathop{\overset{|}{\mathop{C}}\,}}\,}}\,}}\,-O{{C}_{2}}{{H}_{5}}}}\,\xrightarrow{{}}\underset{(B)}{\mathop{{{C}_{6}}{{H}_{5}}-\underset{C{{H}_{3}}}{\mathop{\underset{|}{\mathop{\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,}}\,}}\,-{{C}_{2}}{{H}_{5}}OMgBr}}\,\] \[\underset{(C)}{\mathop{\xrightarrow{C{{H}_{3}}MgBr}{{C}_{6}}{{H}_{5}}-\underset{C{{H}_{3}}}{\mathop{\underset{|}{\mathop{\overset{OMgBr}{\mathop{\overset{|}{\mathop{C}}\,}}\,}}\,}}\,-C{{H}_{3}}}}\,\xrightarrow{{{H}_{3}}{{O}^{+}}}\] \[\underset{{}}{\mathop{{{C}_{6}}{{H}_{5}}-\underset{C{{H}_{3}}}{\mathop{\underset{|}{\mathop{\overset{OH}{\mathop{\overset{|}{\mathop{C}}\,}}\,}}\,}}\,-C{{H}_{3}}}}\,\]


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