JEE Main & Advanced Chemistry Redox Reactions / रेडॉक्स अभिक्रियाएँ Question Bank Redox reaction and Method for balancing redox reaction

  • question_answer
    For the redox reaction \[MnO_{4}^{-}+{{C}_{2}}O_{4}^{-2}+{{H}^{+}}\to \,M{{n}^{2+}}+C{{O}_{2}}+{{H}_{2}}O\] the correct coefficients of the reactants for the balanced reaction are    [IIT 1988, 92; BHU 1995; CPMT 1997; RPMT 1999; DCE 2000; MP PET 2003]

    A)                 \[MnO_{4}^{-}\]                              \[{{C}_{2}}O_{4}^{2-}\]                 \[{{H}^{+}}\]                  2                             5                              16

    B)                 16                           5                              2

    C)                 5                              16                           2

    D)                 2                              16                           5

    Correct Answer: A

    Solution :

           \[MnO_{4}^{-}+8{{H}^{+}}+5{{e}^{-}}\to M{{n}^{2+}}+4{{H}_{2}}O\times 2\]                                 \[{{C}_{2}}O_{4}^{2-}\to 2C{{O}_{2}}+2{{e}^{-}}\times 5\]    \[\overline{2MnO_{4}^{-}+5{{C}_{2}}O_{4}^{2-}+16{{H}^{+}}\to 2M{{n}^{2+}}+10C{{O}_{2}}+8{{H}_{2}}O}\]                                 Thus the coefficient of \[MnO_{4}^{-}\], \[{{C}_{2}}O_{4}^{2-}\]and\[{{H}^{+}}\]in the above balanced equation respectively are 2, 5, 16.


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