JEE Main & Advanced Chemistry Alcohols, Phenols and Ethers / एल्कोहॉल, फीनॉल तथा ईथर Question Bank Properties of alcohol Phenol and Ethers

  • question_answer
    Reaction of phenol with chloroform/sodium hydroxide to give \[o\]-hydroxy benzaldehyde involves the formation of [J & K 2005]

    A)                 Dichloro carbene             

    B)                 Trichloro carbene

    C)                 Chlorine atoms

    D)                 Chlorine molecules

    Correct Answer: A

    Solution :

               This is Reimer-Tiemann reaction where the electrophile is dichlorocarbene \[(:CC{{l}_{2}})\] generated from chloroform by the action of a base.                                 \[O{{H}^{-}}+CHC{{l}_{3}}\]⇌ \[HOH+:CCl_{2}^{-}\to C{{l}^{-}}+:CC{{l}_{2}}\]


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