JEE Main & Advanced Chemistry Chemical Bonding and Molecular Structure / रासायनिक आबंधन एवं आणविक संरचना Question Bank Molecular orbital theory

  • question_answer
    Bond order of \[{{O}_{2}}\]is      [DPMT  2004]

    A)                 2             

    B)                         1.5

    C)                 3             

    D)                 3.5

    Correct Answer: A

    Solution :

               Electronic configuration of \[{{O}_{2}}\] is                    \[{{O}_{2}}={{(\sigma 1s)}^{2}}{{({{\sigma }^{*}}1s)}^{2}}{{(\sigma 2s)}^{2}}{{({{\sigma }^{*}}2s)}^{2}}{{({{\sigma }^{*}}2s)}^{2}}{{(\sigma 2{{p}_{z}})}^{2}}\]                    \[(\pi 2p_{x}^{2}\equiv \pi 2p_{y}^{2})\ ({{\pi }^{*}}2p_{x}^{1}\equiv {{\pi }^{*}}2p_{y}^{1})\]                                 Hence bond order \[=\frac{1}{2}\left[ {{N}_{b}}-{{N}_{a}} \right]\] \[=\frac{1}{2}[10-6]=2\].


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