JEE Main & Advanced Chemistry Solutions / विलयन Question Bank Mock Test - Solutions

  • question_answer
    How many grams of sucrose (M. wt. = 342) should be dissolved in 100 g water in order to produce a solution with a \[105.0{}^\circ C\] difference between the boiling point and the freezing temperatures? \[({{K}_{f}}=\text{ }1.86\text{ }C\text{/}m,\,\,{{K}_{b}}=0.51{}^\circ C\text{/}m)\]

    A) 34.2 g  

    B) 72 g

    C) 342 g   

    D) 460 g

    Correct Answer: B

    Solution :

    [b] \[{{T}_{b}}-{{T}_{f}}=105=100+5\] \[{{T}_{b}}-{{T}_{b}}^{0}-{{T}_{f}}=5\]      \[[\because {{T}_{b}}^{o}=100{}^\circ C]\] \[\Delta {{T}_{b}}-{{T}_{f}}+{{T}_{f}}^{o}-{{T}_{f}}^{o}=5\]  \[\Rightarrow \Delta {{T}_{b}}+\Delta {{T}_{f}}=5\]             \[[\because {{T}_{f}}^{o}=0{}^\circ C]\] \[\Delta {{T}_{f}}+\Delta {{T}_{b}}=m({{k}_{f}}+{{k}_{b}})\] \[\Delta {{T}_{f}}+\Delta {{T}_{b}}=5=\frac{x}{\frac{342}{\frac{100}{1000}}}(1.86+0.51)\] \[5=\frac{10x}{342}\times 2.37\Rightarrow x=72\,g\]


You need to login to perform this action.
You will be redirected in 3 sec spinner