JEE Main & Advanced Chemistry Solutions / विलयन Question Bank Mock Test - Solutions

  • question_answer
    The degree of dissociation (1) of a weak electrolyte \[{{A}_{x}}{{B}_{y}}\] is related to van't Hoff factor (i) by the expression

    A) \[\alpha =\frac{i-1}{(x+y-1)}\]

    B) \[\alpha =\frac{i-1}{x+y+1}\]

    C) \[\alpha =\frac{x+y-1}{i-1}\]                 

    D) \[\alpha =\frac{x+y+1}{i-1}\]

    Correct Answer: A

    Solution :

    [a] van?t Hoff factor (i) is related degree of dissociation (\[\alpha \]) as \[\alpha =\frac{i-1}{n-1}\] Here, n are the moles of an electrolyte \[\left( A-B \right)\] dissolve in a solvent. For \[{{A}_{x}}{{B}_{y}},{{A}_{x}}{{B}_{y}}\rightleftharpoons x{{A}^{+y}}+y{{B}^{-x}}\] Therefore, \[\alpha =\frac{i-1}{(x+y-1)}\]


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