JEE Main & Advanced Chemistry Analytical Chemistry Question Bank Mock Test - Principles Related to Practical Chemistry

  • question_answer
    Which one of the following can be used in place of \[N{{H}_{4}}Cl\] for the identification of the third group radicals?

    A) \[N{{H}_{4}}N{{O}_{3}}\]      

    B) \[{{(N{{H}_{4}})}_{2}}S{{O}_{4}}\]

    C) \[{{(N{{H}_{4}})}_{2}}C{{O}_{3}}\]              

    D) \[NaCl\]

    Correct Answer: A

    Solution :

    [a] As it provides \[N{{H}^{+}}_{4}\]ions which suppresses the ionization of \[N{{H}_{4}}OH\]so that only the group III cations are precipitated as hydroxides because of their low solubility products and \[N{{O}^{-}}_{3}\]ions do not produce precipitate with the cations of IVth, Vth and VIth groups.


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