JEE Main & Advanced Chemistry Analytical Chemistry Question Bank Mock Test - Principles Related to Practical Chemistry

  • question_answer
    An aqueous solution of a substance gives a white precipitate on treatment with dilute hydrochloric acid, which dissolves on heating. When hydrogen sulfide is passed through the hot acidic solution, black precipitate is obtained. The substance is a

    A) \[Hg_{2}^{2+}\]salt    

    B) \[C{{u}^{2+}}\]salt

    C) \[A{{g}^{2+}}\]salt    

    D) \[P{{b}^{2+}}\]salt

    Correct Answer: D

    Solution :

    [d] \[PbC{{l}_{2}}\]is soluble in hot water, and insoluble in cold water. \[P{{b}^{2+}}+2HCl\to \underset{\begin{smallmatrix}  white\,ppt.so\,\operatorname{lub}\,le \\  on\,heating \end{smallmatrix}}{\mathop{PbC{{l}_{2}}}}\,\downarrow \xrightarrow{{{H}_{2}}S}\underset{Black\,ppt.}{\mathop{PbS}}\,\]


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