12th Class Chemistry Alcohols, Phenols and Ethers / एल्कोहॉल, फीनॉल तथा ईथर Question Bank MCQs - Alcohols, Phenols and Ethers

  • question_answer
    Vapours of an alcohol X when passed over hot reduced copper, produce an alkene, the alcohol is

    A) primary alcohol

    B) secondary alcohol

    C) tertiary alcohol

    D) dihydric alcohol.

    Correct Answer: C

    Solution :

    Primary alcohols on dehydration give aldehydes, secondary alcohols give ketones and tertiary alcohols give alkenes. \[RC{{H}_{2}}OH\xrightarrow[\Delta ]{Cu}RCHO\] \[R-\underset{{}}{\overset{\begin{smallmatrix} OH \\ | \end{smallmatrix}}{\mathop{CH}}}\,-R\xrightarrow[\Delta ]{Cu}R-\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,-R\] \[C{{H}_{3}}-\underset{\begin{smallmatrix} | \\  C{{H}_{3}} \end{smallmatrix}}{\overset{\begin{smallmatrix}  C{{H}_{3}} \\ | \end{smallmatrix}}{\mathop{C}}}\,-OH\xrightarrow[\Delta ]{Cu}C{{H}_{3}}-\overset{\begin{smallmatrix}  C{{H}_{3}} \\ | \end{smallmatrix}}{\mathop{C}}\,=C{{H}_{2}}\]


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