12th Class Chemistry Alcohols, Phenols and Ethers / एल्कोहॉल, फीनॉल तथा ईथर Question Bank MCQs - Alcohols, Phenols and Ethers

  • question_answer
    Unlike phenol, 2, 4-dinitrophenol is soluble in sodium carbonate solution in water because

    A) presence of two —\[N{{O}_{2}}\] groups in the ring makes 2, 4-dinitrophenol a stronger acid than phenol

    B) presence of two —\[N{{O}_{2}}\] groups in the ring makes 2, 4-dinitrophenol a weaker acid than phenol

    C) presence of two —\[N{{O}_{2}}\] groups make the hydrogen bonding easier, making 2, 4-dinitrophenol soluble

    D) nitro group reacts with \[N{{a}_{2}}C{{O}_{3}}\] while —OH group does not.

    Correct Answer: A

    Solution :

    Presence of two electron withdrawing -\[N{{O}_{2}}\] groups in the ring makes 2, 4-dinitrophenol a stronger acid than phenol. Hence, it reacts with aqueous \[N{{a}_{2}}C{{O}_{3}}\] solution to form sodium salt thus making it soluble in \[N{{a}_{2}}C{{O}_{3}}\].


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