JEE Main & Advanced Chemistry Solutions / विलयन Question Bank Ideal and Non-ideal solution

  • question_answer
    A non-ideal solution was prepared by mixing 30 ml chloroform and 50 ml acetone. The volume of mixture will be             [Pb. CET 2003]

    A) > 80 ml 

    B) < 80 ml

    C) = 80 ml 

    D) \[\ge \] 80 ml

    Correct Answer: B

    Solution :

     Chloroform & acetone form a non-ideal solution, in which \[A.....B\] type interaction are more than \[A......A\] & \[B......B\] type interaction due to \[H\]-bonding. Hence, the solution shows, negative deviation from Raoult's Law i.e.,                    \[\Delta {{V}_{mix}}=-ve\];   \[\Delta {{H}_{mix}}=-ve\]                    \[\therefore \] total volume of solution = less than (30 + 50 ml)                                  or \[<\,80\,ml\] 


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