JEE Main & Advanced Chemistry Thermodynamics / रासायनिक उष्मागतिकी Question Bank First law of thermodynamics and Hess law

  • question_answer
    The work done in ergs for the reversible expansion of one mole of an ideal gas from a volume of 10 litres to 20 litres at \[{{25}^{o}}C\] is         [CMC Vellore 1991]

    A)                 \[2.303\times 298\times 0.082\,\log \,2\]

    B)                 \[298\times {{10}^{7}}\times 8.31\times 2.303\,\log \,2\]

    C)                 \[2.303\times 298\times 0.082\,\log \,0.5\]

    D)                 \[8.31\times {{10}^{7}}\times 298-2.303\,\log \,0.5\]

    E)                 \[2.303\times 298\times 2\,\log \,2\]

    Correct Answer: B

    Solution :

           \[W=2.303\,\,nRT\log \frac{{{V}_{2}}}{{{V}_{1}}}\]    \[=2.303\,\,\times 1\,\,\times 8.314\,\,\times {{10}^{7}}\,\times 298\,\log \frac{20}{10}\]                                 \[=298\,\,\times {{10}^{7}}\,\times 8.314\,\,\times 2.303\,\,\log \,\,2\].


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