JEE Main & Advanced Chemistry Equilibrium / साम्यावस्था Question Bank Critical Thinking

  • question_answer
    A precipitate of \[Ca{{F}_{2}}\,\,({{K}_{sp}}=1.7\times {{10}^{-10}})\] will be obtained when equal volume of the following are mixed [MP PMT 1990, 95; IIT 1982; MNR 1992]

    A)                 \[{{10}^{-4}}M\,C{{a}^{2+}}\] and \[{{10}^{-4}}M\,{{F}^{-}}\]

    B)                  \[{{10}^{-2}}M\,C{{a}^{2+}}\] and \[{{10}^{-3}}M\,{{F}^{-}}\]

    C)                 \[{{10}^{-5}}M\,C{{a}^{2+}}\] and \[{{10}^{-4}}M\,{{F}^{-}}\]

    D)                 \[{{10}^{-3}}M\,C{{a}^{2+}}\] and \[{{10}^{-4}}M\,{{F}^{-}}\]

    Correct Answer: B

    Solution :

                    \[[C{{a}^{2+}}]\,\,{{[{{F}^{-}}]}^{2}}=\left[ \frac{{{10}^{-2}}\times V}{2V} \right]\times {{\left[ \frac{{{10}^{-3}}\times V}{2V} \right]}^{2}}\]\[=1.25\times {{10}^{-9}}\].


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