JEE Main & Advanced Chemistry Equilibrium / साम्यावस्था Question Bank Critical Thinking

  • question_answer
    At constant temperature, the equilibrium constant (Kp) for the decomposition reaction \[{{N}_{2}}{{O}_{4}}\]⇌\[2N{{O}_{2}}\] is expressed by\[{{K}_{P}}=\frac{(4{{x}^{2}}P)}{(1-{{x}^{2}})}\],           where \[P=\] pressure, \[x=\] extent of decomposition. Which one of the following statements is true [IIT Screening 2001]

    A)                 Kp increases with increase of P

    B)                 Kp increases with increase of x

    C)                 Kp increases with decrease of x

    D)                 Kp remains constant with change in P and x

    Correct Answer: D

    Solution :

                    \[{{K}_{p}}\] (equilibrium constant) is independent of pressure and concentration.


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