JEE Main & Advanced Chemistry Electrochemistry / विद्युत् रसायन Question Bank Critical Thinking Electrochemistry

  • question_answer
    4.5g of aluminium (at mass 27amu) is deposited at cathode from \[A{{l}^{3+}}\] solution by a certain quantity of electric charge. The volume of hydrogen produced at STP from \[{{H}^{+}}\] ions in solution by the same quantity of electric charge will be [CBSE PMT 2005]

    A)                 22.4 L    

    B)                 44.8 L

    C)                 5.6 L      

    D)                 11.2 L

    Correct Answer: C

    Solution :

                Eq of \[Al\]= eq of \[{{H}_{2}}\]                     \[\frac{4.5}{\frac{27}{3}}=\]eq of \[{{H}_{2}}\];  \[\frac{4.5}{9}=\]eq of \[{{H}_{2}}\]                     \[2{{H}^{+}}+2{{e}^{-}}\to {{H}_{2}}\]                    eq. of \[{{H}_{2}}\] = Number of moles × n factor \[0.5=\,{{n}_{{{H}_{2}}}}\times 2\]                                 \[{{V}_{{{H}_{2}}}}=\frac{0.5}{2}\times 22.4\]; \[{{V}_{{{H}_{2}}}}=5.6\ L\]


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